|
|
(22S,24R)-22-hydroxy-5alpha-ergostan-3-one + reduced_flavodoxin + O2 <=> 3-dehydro-6-deoxoteasterone + flavin + H2O
|
1.14.14.147
3-epi-6-deoxocathasterone 23-monooxygenase
|
–
|
K
|
|
BRENDA:
BR49135
KEGG:
R07791
|
|
|
|
(22S,24R)-22-hydroxy-5alpha-ergostan-3-one + NADP+ <=> H+ + (22S)-22-hydroxycampest-4-en-3-one + NADPH
|
1.3.1
1.3.1.22
3-oxo-5alpha-steroid 4-dehydrogenase (NADP+)
|
–
–
|
MK
|
|
KEGG:
R07447
MetaCyc:
RXN-4229
|
|
|
|
5alpha-campestan-3-one + O2 + NADPH <=> (22S,24R)-22-hydroxy-5alpha-ergostan-3-one + NADP+ + H2O
|
1.14.13
|
–
|
K
|
|
KEGG:
R07453
|
|
|
|
(22S,24R)-22-hydroxy-5alpha-ergostan-3-one <=> 6-deoxocathasterone
|
not assigned
|
–
|
K
|
|
KEGG:
R07472
|
|
|
|
(22S,24R)-22-hydroxy-5alpha-ergostan-3-one <=> 3-epi-6-deoxocathasterone
|
not assigned
|
–
|
K
|
|
KEGG:
R07788
|
|
|
|
(22S,24R)-22-hydroxy-5alpha-ergostan-3-one + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 3-dehydro-6-deoxoteasterone + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.147
3-epi-6-deoxocathasterone 23-monooxygenase
|
–
|
M
|
|
MetaCyc:
RXN-11101
|
|
|
|
3-epi-6-deoxocathasterone + acceptor <=> reduced_acceptor + (22S,24R)-22-hydroxy-5alpha-ergostan-3-one
|
1.1.99.M2
|
–
|
M
|
|
MetaCyc:
RXN-11532
|
|
|
|
6-deoxocathasterone + acceptor <=> (22S,24R)-22-hydroxy-5alpha-ergostan-3-one + reduced_acceptor
|
1.1
|
–
|
M
|
|
MetaCyc:
RXN-4228
|
|
|
|
5alpha-campestan-3-one + O2 + reduced_[NADPH-hemoprotein_reductase] <=> (22S,24R)-22-hydroxy-5alpha-ergostan-3-one + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14
|
–
|
M
|
|
MetaCyc:
RXN-4230
|
|